STERLING-CLARK-LURTON CORP -- METHANOL -- -
===================== Product Identification ===================== Product ID:METHANOL MSDS Date:09/01/1990 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:STERLING-CLARK-LURTON CORP Address:184 COMMERCIAL ST Box:J City:MALDEN State:MA ZIP:02148 Country:US Info Phone Num:617-322-0163 Emergency Phone Num:781-440-0900 CAGE:0C5E2 === Contractor Identification === Company Name:STERLING-CLARK-LURTON CORP Address:184 COMMERCIAL ST Box:J City:MALDEN State:MA ZIP:02148 Country:US Phone:617-322-0163 CAGE:0C5E2 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL CAS:67-56-1 RTECS #:PC1400000 OSHA PEL:260 MG/M3;200 PPM ACGIH TLV:262 MG/M3;200 PPM ACGIH STEL:328 MG/M3;250 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:INGESTION-POSIONOUS IF SWALLOWED. CAN AFFECT NERVE RESULTING IN BLINDNESS. SKIN CONTACT-ESSENTIALLY NON-IRRITATING. EYE CONTACT-MAY CAUSE EYE INJURY WHICH MAY PERSISTS FOR SEVERAL DAYS. CHRONIC: MUTAG ENICITY, IN VITRO, LIMITED EVIDENCE OF MUTAGENICITY (MOUSELYMPHOMA FORWARD NUTATION ASSAY). IN VIVO, NO INFORMATION. Explanation of Carcinogenicity:NO EVIDENCE OF CARCINOGENIC POTENTIAL IN LIMITED ANIMAL STUDIES IN WHICH METHANOL WAS GIVEN ORALLY OR APPLIED TO THE SKIN. Effects of Overexposure:NGESTION (SWALLOWING): CAN AFFECT NERVE RESULTING IN BLINDNESS. CAN CAUSE MEDICAL SLUGGISHNESS, NAUSEA AND VOMITING LEADING TO SEVERE ILLNESS, POSSIBLY DEATH (IN HUMANS). INHALATION (BREATHING): EXTR EMELY HIGH LEVELS CAUSE STUPOR, HEADACHE, DIZZINESS AND UNCONSCIOUSNESS. SKIN CONTACT: REPEATED OR PROLONGED CONTACT CAUSES DRYING, BRITTLENESS CRACKING AND IRRITATION. EYE CONTACT: LIQUID AND VAPOR IN HIGH CONCENTRATIONS, CAUSES IRRITATION, TEARING & BURNING SENSATION. Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CONTACT A PHYSICIAN IMMEDIATELY. REMOVE CONTAMINATED CLOTHING AND WASH CONTAMINATED SKIN WITH LARGE AMOUNTS OF WATER. IF IRRITATION PERSIST S, CONTACT A PHYSICIAN. INHALATION:REMOVE PATIENT FROM CONTAMINATED AREA. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION, THEN OXYGEN IF NEEDED. CONTACT A PHYSICIAN IMMEDIATELY. INGESTION: INDU CE VOMITING OF CONSCIOUS PATIENT IMMEDIATELY BY GIVING TWO GLASSES OF WATER AND PRESSING FINGER DOWN THROAT. CONTACT A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=12.2C, 54.F Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL, CARBON DIOXIDE AND VAPORIZING LIQUID TYPE EXTINGUISHING AGENTS MAY ALL BE SUITABLE FOR EXTINGUISHING FIRES INVOLVING THIS TYPE OF PRODUCT, DEP Fire Fighting Procedures:USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO EXTINGUISH THE FIRE. WATER MAY BE INEFFECTIVE, BUT WATER SHOULD BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. IF A LEAK OR SPILL HAS IGNITED, USE WATER SPRQ AY DISPERSE THE VAPORS AND TO PROTECT MEN ATTEMPTING TO STOP A LEAK. Unusual Fire/Explosion Hazard:WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOSURES. MINIMIZE BREAHING GASES, VAPOR, FUMES OR DECOMPOSITION PRODUCTS. USE SUPPLIED-AIR BREATHING EQUIPMENT FOR ENCLOSED OR CONFINED SPACES OR AS OTHERWISE NEEDED. ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF & ELIMINATE IGNITION SOURCES: KEEP PEOPLE AWAY. RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER SUITABLE ABSORBENT TO SPILL AREA. MINIMIZE BREATHING VAPORS. MINIMIZE SKIN CONTACT. VENTILATE CO NFINED SPACES. OPEN ALL WINDOWS & DOORS. KEEP PRODUCT OUT OF SEWERS & WATERCOURSES BY DIKING OR IMPOUNDING. ADVISE AUTHORITIES IF PRODUCT HAS ENTERED OR MAY ENTER SEWERS WATERCOURSES, OR LAND AREAS. ====================== Handling and Storage ====================== Handling and Storage Precautions:THIS LIQUID IS VOLATILE AND GIVES OFF INVISIBLE VAPORS. EITHER THE LIQUID OR VAPOR MAY SETTLE IN LOW AREAS OR TRAVEL SOME DISTANCE ALONG THE GROUND OR SURFACE TO IGNITION SOURCES WHERE THEY MAY IGNITE OR EXPLODE. Other Precautions:KEEP PRODUCT AWAY FROM IGNITION SOURCES, (HEAT, SPARKS, PILOT LIGHTS, STATIC ELECTRICITY, OPEN FLAMES). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED. Ventilation:USE ONLY WITH VENTILATION SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED EXPOSURE LIMIT/BUILDUP OF EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL CONCENTRATION Protective Gloves:USE CHEMICAL-RESISTANT GLOVES, IF NEEDED, TO AVOID PROLONGED/ REPEATED CONTACT. Eye Protection:USE SPLASH GOGGLES OR FACE SHIELD WHEN EYE CONTACT MAY OCCUR. Other Protective Equipment:USE CHEMICAL RESISTANT APRON OR OTHER IMPERVIOUS CLOTHING, IF NEEDED, TO AVOID CONTAMINATING REGULAR CLOTHING, WHICH COULD RESULT IN PROLONGED OR REPEATED SKIN CONTACT. Work Hygienic Practices:MINIMIZE BREATHING VAPOR OR MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. REMOVE CONTAMINATED CLOTHING; LAUNDER OR DRY-CLEAN BEFORE REUSE. REMOVE CONTAMINATED SHOES & CLEAN BEFORE RESUE. Supplemental Safety and Health KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT STORE NEAR HEAT, SPARK, FLAME OR STRONG OXIDANT. TO PREVENT FIRE OR EXPLOSION RISK FROM STATIC ACCUMULATION & DISCHARGE, EFFECTIVELY GROUND TRANSFER SYSTE M. **CLEANSE SKIN AFTER CONTACT, BEFORE BREAS & MEALS, & AT THE END OF WORK PERIOD. ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:=64.4C, 148.F Melt/Freeze Pt:=-97.6C, -144.F Vapor Pres:96.0 MM HG Vapor Density:1.11 Spec Gravity:0.7925 Evaporation Rate & Reference:2.0 Solubility in Water:1 ATM. AND 25 C (77) Appearance and Odor:CLEAR, COLORLESS, MOBILE LIQUID WITH MILD ALCOHOL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH SULFURIC AND OXIDIZING AGENTS. =================== Toxicological Information =================== Toxicological Information:INGESTION: PRACTICALLY NON-TOXIC TO ANIMALS (ORAL LD50, RATS 7.5 G/KG). INHALATION (BREATHING): PRACTICALLY NON-TOXIC TO ANIMALS (INHALATIONLC50 RATS 4 HRS: 64,000 PPM). SKIN CONTACT: SLIGHTLY TOXIC T O ANIMALS BY ABSORPTION (DERMAL LD50, RABBITS: 20 G/KG. REPRODUCTION: METHANOL-REPORTED TO CAUSE BIRTH DEFECTS IN RATS EXPOSED TO VERY HIGH LEVELS OF VAPORS (20,000 PPM). =================== MSDS Transport Information =================== Transport Information:DOT IDENTIFICATION NUMBER: METHANOL/FLAMMABLE LIQUID/UN 1230. DANGER! FLAMMABLE. ===================== Regulatory Information ===================== SARA Title III Information:SARA SECTIONS 301-304: NO TPQ FOR PRODUCT OR ANY CONSTITUENT GREATER THAN 1% OR 0.1% (CARCINOGEN). SARA SECTION 313: THIS PRODUCT CONTAINS APPROXIMATELY 100% METHANOL. SARA SECTION 211-312: ACUTE HAZA RD, CHRONIC HAZARD, FIRE HAZARD. Federal Regulatory Information:THE RQ FOR METHANOL IS 5,000 POUNDS. THIS PRODUCT CONTAINS APPROXIMATELY 100% METHANOL. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.